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We examine microfluidic droplet formation using mixtures of immiscible and miscible fluids and develop a method for determining interfacial tension. 

Abstract We develop original flow-based methods to interrogate and manipulate out-of-equilibrium behaviour of ternary fluids systems at the small scale. In particular, we examine droplet and jet formation of ternary fluid systems in coaxial microchannels when an aqueous phase is injected into a solvent-rich oil phase using common fluids, such as ethanol for the aqueous phase, silicone oil for the oil phase and isopropanol for the solvent. Alcohols are often employed to impart oil and water properties with a myriad of practical uses as extractants, antiseptics, wetting agents, emulsifiers or biofuels. Here, we systematically examine the role of alcohol solvents on the hydrodynamic stability of aqueous–oil multiphase flows in square microchannels. Broad variations of flow rates and solvent concentration reveal a variety of intriguing droplet and jet flow regimes in the presence of spontaneous emulsification phenomena and significant mass transfer across the fluid interface. Typical flow patterns include dripping and jetting droplets, phase inversion and dynamic wetting and conjugate jets. Functional relationships are developed to model the evolution of multiphase flow characteristics with solvent concentration. This work provides insights into complex natural phenomena relevant to the application of microfluidic droplet systems to chemical assays as well as fluid measurement and characterisation technologies. 

We examine the microfluidic postprocessing soft colloidal dispersions and reveal a variety of microflow regimes between nanoscale emulsions and solvents. 

We experimentally study the transition from droplet to wave regimes in microfluidic liquid–liquid multiphase flows having large differences in viscosity. A unified approach based on periodic pattern analysis is employed to study relationships between dispersed and separated flow regimes, including dripping, jetting, capillary waves, inertial waves and core–annular flows over a wide range of flow rates and viscosity contrasts. We examine the morphology and dynamics of each flow regime based on wavelength, frequency and velocity of repeating unit cells to elucidate their connections and to develop predictive capabilities based on dimensionless control parameters. We demonstrate in particular that pattern selection is contingent upon the propagation velocity of droplets and waves at the transition. We also investigate microfluidic wave breaking phenomena with the formation of ligaments and droplets from wave crests in both capillary and inertial wave regimes. This work expands conventional multiphase flow regimes observed in microchannels and shows new routes to disperse highly viscous materials using interfacial waves dynamics in confined microsystems.